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- W2013806912 abstract "The chemical follow-up reactions after one-electron oxidation of p-anisidine (PA), N-methyl-p-anisidine (MPA), and N-benzyl-p-anisidine (BPA) in acetonitrile (AN) were analyzed with a stopped-flow method utilizing the electron-transfer reaction with the tris(p-bromophenyl)amine (TBPA) cation radical. The reactions of these p-anisidine derivative cation radicals in AN were found to be faster than that of N,N-dimethyl-p-anisidine (DMPA) cation radical, which proceeds via the acid−base interaction between DMPA•+ and DMPA. In addition, while the rate law of the decay reaction of DMPA•+ was expressed as −d[DMPA•+]/dt = k[DMPA•+][DMPA], that of PA•+ has been determined to be −d[PA•+]/dt = k[PA•+]2[PA] when PA•+ was generated in the presence of PA. On the other hand, in the case that PA•+ was quantitatively formed without PA via equimolar mixing with TBPA•+, the rate was determined to be −d[PA•+]/dt = k[PA•+]2. Also, for the reactions of MPA•+ and BPA•+, the rate laws were identical to those of PA•+. From these results, the reaction mechanisms and the effects of the methyl groups on the reaction kinetics of the p-anisidine derivative cation radicals in AN were discussed." @default.
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- W2013806912 date "2004-04-14" @default.
- W2013806912 modified "2023-10-12" @default.
- W2013806912 title "Kinetic Analysis of Reactions of <i>p</i>-Anisidine and <i>N</i>-Methyl-<i>p</i>-anisidine Cation Radicals in Acetonitrile Using an Electron-Transfer Stopped-Flow Method" @default.
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- W2013806912 doi "https://doi.org/10.1021/jp035579c" @default.
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