Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013809977> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2013809977 endingPage "346" @default.
- W2013809977 startingPage "333" @default.
- W2013809977 abstract "Abstract Carbon tetrachloride quenches the intensity and lifetime of the room-temperature fluorescence of poly(methylpropylsilane) and its model compounds, permethylated n-decasilane and n-hexadecasilane, in n-hexane and n-hexadecane. The process is dominated by static quenching. Changes in fluorescence shape as a function of quencher concentration show that the lowest energy chromophores extend most in space, supporting the standard segment model of polysilane electronic structure. The usual analysis leads to static quenching volumes of approximately 1800 A3 for Si10Me22 and approximately 3500 A3 for Si16Me34. Unlike these, the quenching volume of poly(methylpropylsilane) depends on the excitation wavelength (approximately 800–1400 A3). It is much larger than that of poly(di-n-hexylsilane), which depends strongly on excitation wavelength (approximately 10–1200 A3). A tentative interpretation of these unusual observations is proposed." @default.
- W2013809977 created "2016-06-24" @default.
- W2013809977 creator A5024710133 @default.
- W2013809977 creator A5045479059 @default.
- W2013809977 creator A5053495413 @default.
- W2013809977 creator A5070425009 @default.
- W2013809977 date "1992-01-01" @default.
- W2013809977 modified "2023-09-30" @default.
- W2013809977 title "Models for polysilane high polymers. Room-temperature solution fluorescence quenching in linear Si10Me22, Si16Me34 and poly(methylpropylsilane) by carbon tetrachloride" @default.
- W2013809977 cites W1988168939 @default.
- W2013809977 cites W1991289402 @default.
- W2013809977 cites W2000070464 @default.
- W2013809977 cites W2008304907 @default.
- W2013809977 cites W2017546804 @default.
- W2013809977 cites W2029432116 @default.
- W2013809977 cites W2032097329 @default.
- W2013809977 cites W2034866958 @default.
- W2013809977 cites W2066291660 @default.
- W2013809977 cites W2083886996 @default.
- W2013809977 cites W2093214308 @default.
- W2013809977 cites W2108439410 @default.
- W2013809977 cites W2949308729 @default.
- W2013809977 doi "https://doi.org/10.1016/1010-6030(92)85063-z" @default.
- W2013809977 hasPublicationYear "1992" @default.
- W2013809977 type Work @default.
- W2013809977 sameAs 2013809977 @default.
- W2013809977 citedByCount "18" @default.
- W2013809977 crossrefType "journal-article" @default.
- W2013809977 hasAuthorship W2013809977A5024710133 @default.
- W2013809977 hasAuthorship W2013809977A5045479059 @default.
- W2013809977 hasAuthorship W2013809977A5053495413 @default.
- W2013809977 hasAuthorship W2013809977A5070425009 @default.
- W2013809977 hasConcept C104779481 @default.
- W2013809977 hasConcept C120665830 @default.
- W2013809977 hasConcept C121332964 @default.
- W2013809977 hasConcept C121745418 @default.
- W2013809977 hasConcept C127413603 @default.
- W2013809977 hasConcept C140205800 @default.
- W2013809977 hasConcept C159985019 @default.
- W2013809977 hasConcept C178790620 @default.
- W2013809977 hasConcept C185592680 @default.
- W2013809977 hasConcept C188027245 @default.
- W2013809977 hasConcept C192562407 @default.
- W2013809977 hasConcept C2777359374 @default.
- W2013809977 hasConcept C2777764424 @default.
- W2013809977 hasConcept C42360764 @default.
- W2013809977 hasConcept C521977710 @default.
- W2013809977 hasConcept C75473681 @default.
- W2013809977 hasConcept C91881484 @default.
- W2013809977 hasConceptScore W2013809977C104779481 @default.
- W2013809977 hasConceptScore W2013809977C120665830 @default.
- W2013809977 hasConceptScore W2013809977C121332964 @default.
- W2013809977 hasConceptScore W2013809977C121745418 @default.
- W2013809977 hasConceptScore W2013809977C127413603 @default.
- W2013809977 hasConceptScore W2013809977C140205800 @default.
- W2013809977 hasConceptScore W2013809977C159985019 @default.
- W2013809977 hasConceptScore W2013809977C178790620 @default.
- W2013809977 hasConceptScore W2013809977C185592680 @default.
- W2013809977 hasConceptScore W2013809977C188027245 @default.
- W2013809977 hasConceptScore W2013809977C192562407 @default.
- W2013809977 hasConceptScore W2013809977C2777359374 @default.
- W2013809977 hasConceptScore W2013809977C2777764424 @default.
- W2013809977 hasConceptScore W2013809977C42360764 @default.
- W2013809977 hasConceptScore W2013809977C521977710 @default.
- W2013809977 hasConceptScore W2013809977C75473681 @default.
- W2013809977 hasConceptScore W2013809977C91881484 @default.
- W2013809977 hasIssue "3" @default.
- W2013809977 hasLocation W20138099771 @default.
- W2013809977 hasOpenAccess W2013809977 @default.
- W2013809977 hasPrimaryLocation W20138099771 @default.
- W2013809977 hasRelatedWork W1991734736 @default.
- W2013809977 hasRelatedWork W2009097323 @default.
- W2013809977 hasRelatedWork W2050000269 @default.
- W2013809977 hasRelatedWork W2068676208 @default.
- W2013809977 hasRelatedWork W2072137565 @default.
- W2013809977 hasRelatedWork W2148041654 @default.
- W2013809977 hasRelatedWork W2306649710 @default.
- W2013809977 hasRelatedWork W2332217867 @default.
- W2013809977 hasRelatedWork W3031217726 @default.
- W2013809977 hasRelatedWork W3109218211 @default.
- W2013809977 hasVolume "62" @default.
- W2013809977 isParatext "false" @default.
- W2013809977 isRetracted "false" @default.
- W2013809977 magId "2013809977" @default.
- W2013809977 workType "article" @default.