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• W2013812413 abstract "Caged versions of the most common mitochondrial uncouplers (proton translocators) have been prepared that sense the reactive oxygen species (ROS) hydrogen peroxide to release the uncouplers 2,4-dinitrophenol (DNP) and carbonylcyanide p-trifluoromethoxyphenylhydrazone (FCCP) from caged states with second order rate constants of 10 (±0.8) M−1 s−1 and 64.8 (±0.6) M−1 s−1, respectively. The trigger mechanism involves conversion of an arylboronate into a phenol followed by fragmentation. Hydrogen peroxide-activated uncouplers may be useful for studying the biological process of ageing." @default.
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• W2013812413 date "2010-03-01" @default.
• W2013812413 modified "2023-10-14" @default.
• W2013812413 title "Caged mitochondrial uncouplers that are released in response to hydrogen peroxide" @default.
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• W2013812413 doi "https://doi.org/10.1016/j.tet.2010.01.103" @default.
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