FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013816901> ?p ?o ?g. }

• W2013816901 endingPage "541" @default.
• W2013816901 startingPage "534" @default.
• W2013816901 abstract "Abstract The unified equation was validated for first order reactions in dynamic CE with a data set of 31 250 elution profiles. Comparison with the results from conventional iterative computer simulation revealed that the unified equation is superior in terms of success rate and precision. The unified equation was applied to determine the cis‐trans isomerization rate constants of the angiotensin converting enzyme inhibitor captopril. The separation of the rotational cis‐trans isomeric drug has been performed in an aqueous 66 mM citric acid/Tris buffer at pH 3.0 in a 50 cm polyacrylamide‐coated fused‐silica capillary. Interconversion profiles featuring pronounced plateau formation and peak broadening were observed. Activation parameters Δ H ≠ and Δ S ≠ were obtained from temperature‐dependent measurements between 10 and 25°C in 2.5 K steps. From the activation parameters the isomerization barriers of captopril at 37°C under acidic conditions were calculated to be Δ G ≠ trans→cis = 90.6 kJ/mol and Δ G ≠ cis→trans = 84.6 kJ/mol. By comparison of the kinetic data with the results obtained under basic conditions (pH 9.3) a mechanism of isomerization could be proposed." @default.
• W2013816901 created "2016-06-24" @default.
• W2013816901 creator A5079908686 @default.
• W2013816901 date "2006-02-01" @default.
• W2013816901 modified "2023-09-30" @default.
• W2013816901 title "The unified equation for the evaluation of first order reactions in dynamic electrophoresis" @default.
• W2013816901 cites W1535863565 @default.
• W2013816901 cites W1969033628 @default.
• W2013816901 cites W1970849803 @default.
• W2013816901 cites W1974950759 @default.
• W2013816901 cites W1989357687 @default.
• W2013816901 cites W1996556818 @default.
• W2013816901 cites W1997677499 @default.
• W2013816901 cites W1999707366 @default.
• W2013816901 cites W2017244453 @default.
• W2013816901 cites W2017639307 @default.
• W2013816901 cites W2033274884 @default.
• W2013816901 cites W2036863228 @default.
• W2013816901 cites W2059968606 @default.
• W2013816901 cites W2072086585 @default.
• W2013816901 cites W2077180998 @default.
• W2013816901 cites W2077400936 @default.
• W2013816901 cites W2078931933 @default.
• W2013816901 cites W2087266281 @default.
• W2013816901 cites W2088748280 @default.
• W2013816901 cites W2089740373 @default.
• W2013816901 cites W2091385480 @default.
• W2013816901 cites W2094269963 @default.
• W2013816901 cites W2133779697 @default.
• W2013816901 cites W2145050258 @default.
• W2013816901 cites W2952918190 @default.
• W2013816901 doi "https://doi.org/10.1002/elps.200500708" @default.
• W2013816901 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16380957" @default.
• W2013816901 hasPublicationYear "2006" @default.
• W2013816901 type Work @default.
• W2013816901 sameAs 2013816901 @default.
• W2013816901 citedByCount "39" @default.
• W2013816901 countsByYear W20138169012012 @default.
• W2013816901 countsByYear W20138169012013 @default.
• W2013816901 countsByYear W20138169012014 @default.
• W2013816901 countsByYear W20138169012015 @default.
• W2013816901 countsByYear W20138169012016 @default.
• W2013816901 countsByYear W20138169012019 @default.
• W2013816901 countsByYear W20138169012020 @default.
• W2013816901 crossrefType "journal-article" @default.
• W2013816901 hasAuthorship W2013816901A5079908686 @default.
• W2013816901 hasConcept C113196181 @default.
• W2013816901 hasConcept C121332964 @default.
• W2013816901 hasConcept C126661725 @default.
• W2013816901 hasConcept C126838900 @default.
• W2013816901 hasConcept C135889238 @default.
• W2013816901 hasConcept C147789679 @default.
• W2013816901 hasConcept C148898269 @default.
• W2013816901 hasConcept C161790260 @default.
• W2013816901 hasConcept C178790620 @default.
• W2013816901 hasConcept C184651966 @default.
• W2013816901 hasConcept C185592680 @default.
• W2013816901 hasConcept C2779479957 @default.
• W2013816901 hasConcept C2781014771 @default.
• W2013816901 hasConcept C2900643 @default.
• W2013816901 hasConcept C43617362 @default.
• W2013816901 hasConcept C55493867 @default.
• W2013816901 hasConcept C62520636 @default.
• W2013816901 hasConcept C71924100 @default.
• W2013816901 hasConcept C73826308 @default.
• W2013816901 hasConcept C84393581 @default.
• W2013816901 hasConcept C93391505 @default.
• W2013816901 hasConceptScore W2013816901C113196181 @default.
• W2013816901 hasConceptScore W2013816901C121332964 @default.
• W2013816901 hasConceptScore W2013816901C126661725 @default.
• W2013816901 hasConceptScore W2013816901C126838900 @default.
• W2013816901 hasConceptScore W2013816901C135889238 @default.
• W2013816901 hasConceptScore W2013816901C147789679 @default.
• W2013816901 hasConceptScore W2013816901C148898269 @default.
• W2013816901 hasConceptScore W2013816901C161790260 @default.
• W2013816901 hasConceptScore W2013816901C178790620 @default.
• W2013816901 hasConceptScore W2013816901C184651966 @default.
• W2013816901 hasConceptScore W2013816901C185592680 @default.
• W2013816901 hasConceptScore W2013816901C2779479957 @default.
• W2013816901 hasConceptScore W2013816901C2781014771 @default.
• W2013816901 hasConceptScore W2013816901C2900643 @default.
• W2013816901 hasConceptScore W2013816901C43617362 @default.
• W2013816901 hasConceptScore W2013816901C55493867 @default.
• W2013816901 hasConceptScore W2013816901C62520636 @default.
• W2013816901 hasConceptScore W2013816901C71924100 @default.
• W2013816901 hasConceptScore W2013816901C73826308 @default.
• W2013816901 hasConceptScore W2013816901C84393581 @default.
• W2013816901 hasConceptScore W2013816901C93391505 @default.
• W2013816901 hasIssue "3" @default.
• W2013816901 hasLocation W20138169011 @default.
• W2013816901 hasLocation W20138169012 @default.
• W2013816901 hasOpenAccess W2013816901 @default.
• W2013816901 hasPrimaryLocation W20138169011 @default.
• W2013816901 hasRelatedWork W1984980239 @default.
• W2013816901 hasRelatedWork W2011452239 @default.
• W2013816901 hasRelatedWork W2036863228 @default.
• W2013816901 hasRelatedWork W2097879772 @default.
• W2013816901 hasRelatedWork W2380540283 @default.

• next