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- W2013820444 abstract "The coset space representation is employed to study the algebraic molecular vibrational dynamics with SU(2) symmetry. The power of the coset space representation is that with it the quantum effect of the dynamics can be retrieved. It is shown that when J2 ⪢ J, where J is half the total boson number N of the vibrational system, the coset space representation reduces to the classical Heisenberg correspondence. A sample calculation of H2O and O3 systems shows that, for N < 10, the quantum effect neglected in the classical Heisenberg correspondence can be significant. This is evidenced by the different local-normal transitions in these two algorithms." @default.
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- W2013820444 date "1993-06-01" @default.
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- W2013820444 title "The coset space representation of the algebraic molecular vibrational dynamics. Case study of the SU(2) group" @default.
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- W2013820444 doi "https://doi.org/10.1016/0009-2614(93)87220-w" @default.
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