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- W2013829185 abstract "Abstract The MO2(B) lattice is an extensively sheared ReO3 derivative with only 2×2 ReO3 blocks left, and is thus a rather rigid structure. VO2(B), TiO2(B), FeV3O8, and AlNbO4 can all be synthesized with this structure. Chemical lithiation at 25°C resulted in maximal uptakes of 0.8, 0.65, 0.32, and 0.05 Li/MO2 for TiO2(B), VO2(B), FeV3O8, and AlNbO4, respectively. X-ray diffraction of lithiated samples showed virtually no changes of the a, c, and β parameters of the monoclinic cell, while the b-axis exhibited an expansion of ca 5%. AlNbO4 retained its lattice dimensions. Electrochemical Li uptake in cells with LiCF3SO3-PEO electrolyte operated at 100°C with constant current discharge (50 μA/cm2) resulted in uptake of 0.75, 1.0, 0.75, and 1.0 Li/MO2 for TiO2(B), VO2(B), FeV3O8 and AlNbO4. VO2(B), FeV3O8 and AlNbO4 exhibited phase separation, while TiO2(B) inserted Li homogen eously. The potential plateau for LixFeV3O8 was ≈150 mV higher than for LixVO2(B), due to the presence of pentavalent vanadium in FeV3O8." @default.
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- W2013829185 date "1992-07-01" @default.
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- W2013829185 title "Lithium insertion in isomorphous MO2(B) structures" @default.
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- W2013829185 doi "https://doi.org/10.1016/0167-2738(92)90401-a" @default.
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