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- W2013840185 abstract "The thermal degradation of vulcanized elastomeric poly(ethylene-co-vinyl acetate) (EVM) in inert and oxidative conditions was investigated. Based on the characterization of both condensed and gas phases during the thermal degradation it was possible to propose a reaction scheme of the EVM degradation. In addition, the determination of the kinetic parameters completed the chemical investigations. The thermo-oxidation of vulcanized EVM occurs in five steps, including the cleavage of some cross-linking bonds, the catalytic deacetylation forming polyenes and a charring step, followed by the decomposition and oxidation of the char. It appeared that the curing, and thus the cross-linking nodes, enhances the thermal stability of EVM by favouring the charring. On the other hand the pyrolysis of the polymer is quite not influenced by the vulcanization." @default.
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- W2013840185 date "2011-10-01" @default.
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- W2013840185 title "Thermal degradation of elastomeric vulcanized poly(ethylene-co-vinyl acetate) (EVM): Chemical and kinetic investigations" @default.
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- W2013840185 doi "https://doi.org/10.1016/j.polymdegradstab.2011.07.015" @default.
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