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- W2013840857 abstract "The electronic effect parameter σ for XYZSi-R compounds as silyl hydrides XYZSiH, alkoxysilanes XYZSiOL (L = alkyl or substituted alkyl) and α-carbofunctional silanes XYZSiCH 2 Y (Y = Cl and OL) having X, Y and Z substituents of various electron-donating and electronaccepting ability has been established by a linear regression analysis of the IR and NQR data on these compounds. It is shown that no universal scale of the σ constant for silyl XYZSi-groups can be established. The electronic effect transmission of the X, Y and Z substituents through the silicon depends on the type of the intramolecular interaction between the silicon and the R group and the electronic effect parameter of silyl groups should be treated as a variable whose exact value depends on the nature of the particular molecule." @default.
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- W2013840857 date "1980-01-01" @default.
- W2013840857 modified "2023-09-23" @default.
- W2013840857 title "The electronic effect of silyl groups in different XYZSi-R systems" @default.
- W2013840857 doi "https://doi.org/10.1135/cccc19800861" @default.
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