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- W2013842867 abstract "When {2,2′-[(2-methyl-2-nitropropane-1,3-diyl)diimino]diacetato}copper(II), [Cu(C8H13N3O6)], (I), was crystallized from a binary mixture of methanol and water, a monoclinic two-dimensional water- and methanol-solvated metal–organic framework (MOF) structure, distinctly different from the known orthorhombic one-dimensional coordination polymer of (I), was isolated, namely catena-poly[[copper(II)-μ3-2,2′-[(2-methyl-2-nitropropane-1,3-diyl)diimino]diacetato] methanol 0.45-solvate 0.55-hydrate], {[Cu(C8H13N3O6)]·0.45CH3OH·0.55H2O}n, (II). The monoclinic structure of (II) comprises centrosymmetric dimers stabilized by a dative covalent Cu2O2 core and intramolecular N—H⋯O hydrogen bonds. Each dimer is linked to four neighbouring dimers via symmetry-related (opposing) pairs of bridging carboxylate O atoms to generate a `diamondoid' net or two-dimensional coordination network. Tight voids of 166 Å3 are located between these two-dimensional MOF sheets and contain a mixture of water and methanol with fractional occupancies of 0.55 and 0.45, respectively. The two-dimensional MOF sheets have nanometre-scale spacings (11.2 Å) in the crystal structure. Hydrogen-bonding between the methanol/water hydroxy groups and a Cu-bound bridging carboxylate O atom apparently negates thermal desolvation of the structure below 358 K in an uncrushed crystal of (II)." @default.
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- W2013842867 date "2009-08-15" @default.
- W2013842867 modified "2023-09-25" @default.
- W2013842867 title "A bis(amine–carboxylate) copper(II) coordination compound forms a two-dimensional metal–organic framework when crystallized from water and methanol" @default.
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- W2013842867 doi "https://doi.org/10.1107/s010827010903128x" @default.
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