Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013875341> ?p ?o ?g. }
- W2013875341 endingPage "118" @default.
- W2013875341 startingPage "108" @default.
- W2013875341 abstract "A series of silica-supported vanadium oxo complexes has been prepared via water-free grafting VOCl3 onto the silica surface. The obtained materials have been characterized with Raman, diffuse reflectance FTIR (DRIFT) and UV–vis, 51V solid-state NMR and X-ray photoelectron spectroscopies, elemental analysis and N2 physisorption. The samples with a low vanadium loading (1–5%) have been found to be comprised primarily of the isolated tetrahedral d0 units (SiO)V(O)Cl2, whereas the materials with a higher vanadium content are contaminated with a significant amount of d1 vanadium species. The silica-supported vanadium complexes act as heterogeneous catalysts for oxo/imido heterometathesis between N-sulfinylamines and carbonyl compounds affording imines and SO2. Grafting VOCl3 onto silica leads to a dramatic enhancement of its catalytic activity. A novel water-free express method for preparation of imines of wide range of aldehydes and some ketones has been developed. Noteworthy, this is the first example of transition metal mediated heterometathetical imidation of ketones." @default.
- W2013875341 created "2016-06-24" @default.
- W2013875341 creator A5000859124 @default.
- W2013875341 creator A5008342124 @default.
- W2013875341 creator A5012056387 @default.
- W2013875341 creator A5013267685 @default.
- W2013875341 creator A5014534406 @default.
- W2013875341 creator A5021602359 @default.
- W2013875341 creator A5038862983 @default.
- W2013875341 creator A5069648189 @default.
- W2013875341 creator A5088297275 @default.
- W2013875341 date "2011-10-01" @default.
- W2013875341 modified "2023-10-16" @default.
- W2013875341 title "Oxo/imido heterometathesis of N-sulfinylamines and carbonyl compounds catalyzed by silica-supported vanadium oxochloride" @default.
- W2013875341 cites W1607723096 @default.
- W2013875341 cites W182101576 @default.
- W2013875341 cites W1838373603 @default.
- W2013875341 cites W1890678663 @default.
- W2013875341 cites W193502871 @default.
- W2013875341 cites W1967911025 @default.
- W2013875341 cites W1968224425 @default.
- W2013875341 cites W1970019685 @default.
- W2013875341 cites W1972584116 @default.
- W2013875341 cites W1983710458 @default.
- W2013875341 cites W1987079475 @default.
- W2013875341 cites W1993927654 @default.
- W2013875341 cites W2006792934 @default.
- W2013875341 cites W2006966426 @default.
- W2013875341 cites W2007866112 @default.
- W2013875341 cites W2011782218 @default.
- W2013875341 cites W2014159846 @default.
- W2013875341 cites W2018723217 @default.
- W2013875341 cites W2029301069 @default.
- W2013875341 cites W2030384669 @default.
- W2013875341 cites W2035417009 @default.
- W2013875341 cites W2038662926 @default.
- W2013875341 cites W2039035104 @default.
- W2013875341 cites W2043068433 @default.
- W2013875341 cites W2046142803 @default.
- W2013875341 cites W2048796469 @default.
- W2013875341 cites W2051118901 @default.
- W2013875341 cites W2051248161 @default.
- W2013875341 cites W2052259320 @default.
- W2013875341 cites W2053508267 @default.
- W2013875341 cites W2053950022 @default.
- W2013875341 cites W2061966725 @default.
- W2013875341 cites W2062049711 @default.
- W2013875341 cites W2063726108 @default.
- W2013875341 cites W2068043331 @default.
- W2013875341 cites W2070092844 @default.
- W2013875341 cites W2070495772 @default.
- W2013875341 cites W2072512291 @default.
- W2013875341 cites W2073928474 @default.
- W2013875341 cites W2073944536 @default.
- W2013875341 cites W2074769752 @default.
- W2013875341 cites W2075768273 @default.
- W2013875341 cites W2078410461 @default.
- W2013875341 cites W2080419706 @default.
- W2013875341 cites W2082624067 @default.
- W2013875341 cites W2088515014 @default.
- W2013875341 cites W2089978027 @default.
- W2013875341 cites W2091074660 @default.
- W2013875341 cites W2094108755 @default.
- W2013875341 cites W2104288336 @default.
- W2013875341 cites W2104465556 @default.
- W2013875341 cites W2113593163 @default.
- W2013875341 cites W2124345536 @default.
- W2013875341 cites W2137736266 @default.
- W2013875341 cites W2141857771 @default.
- W2013875341 cites W2151327109 @default.
- W2013875341 cites W2159261412 @default.
- W2013875341 cites W2177649978 @default.
- W2013875341 cites W2950496677 @default.
- W2013875341 cites W2950775788 @default.
- W2013875341 cites W2951219356 @default.
- W2013875341 cites W2951514106 @default.
- W2013875341 cites W2951560384 @default.
- W2013875341 cites W2952053300 @default.
- W2013875341 cites W2952300499 @default.
- W2013875341 cites W2953204406 @default.
- W2013875341 cites W2953387986 @default.
- W2013875341 doi "https://doi.org/10.1016/j.jcat.2011.07.011" @default.
- W2013875341 hasPublicationYear "2011" @default.
- W2013875341 type Work @default.
- W2013875341 sameAs 2013875341 @default.
- W2013875341 citedByCount "13" @default.
- W2013875341 countsByYear W20138753412012 @default.
- W2013875341 countsByYear W20138753412013 @default.
- W2013875341 countsByYear W20138753412014 @default.
- W2013875341 countsByYear W20138753412016 @default.
- W2013875341 countsByYear W20138753412017 @default.
- W2013875341 countsByYear W20138753412018 @default.
- W2013875341 countsByYear W20138753412019 @default.
- W2013875341 countsByYear W20138753412020 @default.
- W2013875341 countsByYear W20138753412021 @default.
- W2013875341 crossrefType "journal-article" @default.
- W2013875341 hasAuthorship W2013875341A5000859124 @default.
- W2013875341 hasAuthorship W2013875341A5008342124 @default.