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- W2013883751 abstract "Abstract It has long been known that the crystal structure and the transition temperature of VO2 can be altered by introducing simple and charge coupled substituent ions into crystalline solution. Experiments have been continued in the present study to discover the effect of charge coupled substitutions of the type M3+Nb5+O4 (M Fe or Cr) and M2+M6+O4 (M2+ Ni, Cu or Mn and, M6+ W, Mo or Te). The structural transitions monoclinic-monoclinic-tetragonal or monoclinic-tetragonal have been identified for each composition and their dependence on the amounts of dopants and ionic radii of ions substituted for V4+ determined. The results of the present findings show that the crystalline solutions containing M3++Nb5+ show an initial decrease in the Ttr followed by an increase as M3+NbO4 is added, while in all M6++M2+ substitutions Ttr is always lowered. The substitution of Cr2WO6 and MnWO4 in the binary V1−2xCrxVxO2 crystalline-solution series showed first an increase and then a decrease in the Ttr for these ternarysolid-solutions." @default.
- W2013883751 created "2016-06-24" @default.
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- W2013883751 date "1977-01-01" @default.
- W2013883751 modified "2023-09-24" @default.
- W2013883751 title "Structural and thermal studies on the V1−2xMx3+NbxO2 and V1−2xMx2+Mx6+O2, systems" @default.
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- W2013883751 doi "https://doi.org/10.1016/0022-1902(77)80156-5" @default.
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