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• W2013886542 abstract "Abstract Summary: Isoprene polymerisation performed under microwave irradiation with [Nd(BH 4 ) 3 (THF) 3 ]/Mg(Bu) 2 and [Nd(BH 4 ) 3 (THF) 3 ]/Al(Et) 3 showed an enhancement in reactivity, with selectivity being only slightly modified. An explanation of the observed effect is proposed based on our current knowledge of the catalytic mechanism and by considering the alkylated complex as an ion pair. An analogy is proposed with the pseudoanionic polymerisation of oxygenated monomers. Finally, depolymerisation is observed under microwave irradiation at high temperature. Postulated mechanism for the polymerisation of isoprene with [Nd(BH 4 ) 3 (THF) 3 ]/Mg(Bu) 2 . image Postulated mechanism for the polymerisation of isoprene with [Nd(BH 4 ) 3 (THF) 3 ]/Mg(Bu) 2 ." @default.
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• W2013886542 date "2004-12-28" @default.
• W2013886542 modified "2023-10-11" @default.
• W2013886542 title "The Mechanism of Diene Polymerisation by Organolanthanide Catalysts Deduced from Microwave Experiments" @default.
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• W2013886542 doi "https://doi.org/10.1002/marc.200400434" @default.
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