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- W2013900629 abstract "We study the thiophene-based oligomer poly[2,7-(9,9-bis(2′-ethylhexyl)fluorene)-alt-2,5-terthiophene] (PF3T) in solution and when dispersed at low concentration into a polynorbornene matrix. We find that at high concentration in solution the 0–0 electronic transition observed in fluorescence is suppressed, a result indicative of the formation of weakly coupled H-aggregates. At low concentration in a polymer matrix, emission from both single molecules and molecular aggregates is observed. We find that the fluorescence spectra of most PF3T emitters are composed of a number of relatively narrow emission features, indicating that the emission usually occurs from multiple chromophores. A small number of PF3T molecules are however characterized by single chromophore emission, spectral blinking, and narrowed emission peaks." @default.
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- W2013900629 date "2011-09-30" @default.
- W2013900629 modified "2023-10-16" @default.
- W2013900629 title "Spectroscopy and Single-Molecule Emission of a Fluorene-Terthiophene Oligomer" @default.
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- W2013900629 doi "https://doi.org/10.1021/jp206368g" @default.
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