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- W2013902343 abstract "The crystallinity and crystallization behavior of syndiotactic polystyrene (s-PS) α- and β-crystals have been thoroughly examined using the Fourier Transform Infrared (FTIR). It is shown that absorptivity ratio of respective absorbances of “α-crystal/amorphous, aα” and “β-crystal/amorphous, aβ” can be quantitatively determined using FTIR spectra ranging from 865 to 820 cm−1. Results from curve fitting show that both absorptivity ratios of aα and aβ are 0.178±0.005 and 0.272±0.005 for α- and β-crystal absorbances, respectively. The crystallization rate and crystallinity of α-crystal calculated from the absorptivity ratios are higher than that of β-crystal crystallized at 240°C for the same isothermal duration in thin film sample. The formation of β-crystal is thermodynamically more favorable while of α-crystal is kinetically more favorable from FTIR spectra." @default.
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- W2013902343 date "2001-02-01" @default.
- W2013902343 modified "2023-10-14" @default.
- W2013902343 title "Novel determination of the crystallinity of syndiotactic polystyrene using FTIR spectrum" @default.
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- W2013902343 doi "https://doi.org/10.1016/s0032-3861(00)00849-1" @default.
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