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- W2013920503 abstract "Fe57 Mössbauer spectroscopic studies on an as-synthesized sample of iron silicates with the mordenite topology/mordenite (Fe)/ferrimordenite, which was substantially free from Al (SiO2Al2O3 > 1000), have been carried out at room temperature (RT). 4.2 K, and in the presence of an externally applied magnetic field 4.13 T). The derived hyperfine interaction parameters at RT (IS = 0.24 ± 0.02 mm/s, Δ EQ = 0.59 ± 0.02 mm/s, and at 4.2 K, IS = 0.34 ± 0.02 mm/s, Δ EQ = 0.61 ± 0.02 mm/s), clearly indicated the presence of most of the iron ions at high-spin Fe3+ (6S52) in nearly symmetric tetrahedral sites. Low-temperature/high-magnetic field spectra revealed the average internal field of 460 ± 10 KOe. These results confirm the uniform dispersion of Fe3+ ions in the tetrahedral framework of ferrimordenite." @default.
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- W2013920503 date "1992-02-01" @default.
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- W2013920503 title "Fe57 Mössbauer spectroscopic studies of iron silicates with the mordenite topology" @default.
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- W2013920503 doi "https://doi.org/10.1016/0144-2449(92)90081-y" @default.
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