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- W2013920930 abstract "Low-energy-electron-diffraction analyses of Fe-, Mn-, and Rh-stabilized Au{001}1ifmmodetimeselsetexttimesfi{}1 surfaces find the atomic structure to be a relaxed bulk termination. The first and the second interlayer spacings are contracted by about (2ifmmodepmelsetextpmfi{}2.8)% and (2.8ifmmodepmelsetextpmfi{}2.8)%, respectively, of the bulk spacing along 〈001〉. Photoemission experiments with synchrotron radiation on reconstructed Au{001}5ifmmodetimeselsetexttimesfi{}20 find a surface-resonance band above the bulk d bands which exhibits dispersion with photon energies between 14 and 24 eV, in accordance with the buckled character of the hexagonal overlayer responsible for the surface reconstruction. All remaining features in the photoemission spectra from Au{001}5ifmmodetimeselsetexttimesfi{}20 can be explained on the basis of the self-consistent relativistic calculation of Eckardt, Fritsche, and Noffke to within 0.4 eV. Photoemission from Rh-stabilized Au{001}1ifmmodetimeselsetexttimesfi{}1 is similar to that from the reconstructed surface except for the surface resonance, which is markedly reduced on the 1ifmmodetimeselsetexttimesfi{}1 surface, and a shift of one band which points toward a transfer of s-like charge from the Rh to the Au atoms in the surface region." @default.
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- W2013920930 date "1994-03-15" @default.
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- W2013920930 title "Electronic and crystallographic properties of reconstructed and nonreconstructed Au{001}" @default.
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- W2013920930 doi "https://doi.org/10.1103/physrevb.49.8353" @default.
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