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- W2013971101 abstract "The acidity level and the fluoride ion activity are evaluated in anhydrous HF and in water+HF mixtures of HF content higher than 70% by means of R(H) and R(F) functions. For both functions, the potentials of the ferrocene/ferricinium or perylene+/perylene2+ systems are used as reference potentials. A hydrogen electrode is used for acidity level evaluation and it is shown that the R(H) function decreases (acidity increases) when HF content increases in the mixture; the value of R(H) is −15.5 for anhydrous hydrogen fluoride (+KF 0.1 M). A lanthanum trifluoride monocrystal electrode is built and used for F− activity evaluations and it is shown that the R(F) function increases (activity of fluoride ion decreases) when HF content increases, up to R(F)=13.6 for basic anhydrous HF (KF 0.1 M solution)." @default.
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- W2013971101 date "1975-08-01" @default.
- W2013971101 modified "2023-09-26" @default.
- W2013971101 title "Acidity function R(H) and fluoride ion activity function R(F) in anhydrous hydrogen fluoride and in water+hydrogen fluoride mixtures" @default.
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- W2013971101 doi "https://doi.org/10.1016/s0022-0728(75)80289-0" @default.
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