FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013981452> ?p ?o ?g. }

• W2013981452 endingPage "679" @default.
• W2013981452 startingPage "669" @default.
• W2013981452 abstract "A series of cycloalkylidene-bridged cyclopentadienyl metallocene complexes, [(CH(2))(n)C(C(5)H(4))(2)MCl(2)] (M = Ti, n = 4 (4), 5 (5), 6 (6); M = Zr, n = 4 (7), 5 (8), 6 (9); M = Hf, n = 4 (10), 5 (11), 6 (12)), have been synthesized and applied to ethylene polymerization after activation with methyl aluminoxane (MAO). The cycloalkylidene-bridged titanocene catalysts exhibit much higher activities than the corresponding zirconocene and hafnocene analogues, and have the highest activities at higher temperatures. In comparison, the silacyclopentylidene-bridged metallocene complexes [(CH(2))(4)Si(C(5)H(4))(2)MCl(2)] (M = Ti (13), Zr (14)) and isopropylene-bridged metallocene complexes [Me(2)C(C(5)H(4))(2)MCl(2)] (M = Ti (15), Zr (16)) have also been synthesized and applied to ethylene polymerization. In both cases, the titanocene complexes show much higher activities than the corresponding zirconocene analogues, especially at a lower temperature. The molecular structures of complexes 4-9 have been determined by X-ray diffraction. The structure-activity relationships, especially the effects of the bridges of ansa-metallocene complexes, are discussed." @default.
• W2013981452 created "2016-06-24" @default.
• W2013981452 creator A5003653567 @default.
• W2013981452 creator A5006871407 @default.
• W2013981452 creator A5011394437 @default.
• W2013981452 creator A5011843698 @default.
• W2013981452 creator A5017431309 @default.
• W2013981452 creator A5018984822 @default.
• W2013981452 creator A5027455656 @default.
• W2013981452 creator A5052569205 @default.
• W2013981452 creator A5068762123 @default.
• W2013981452 creator A5070692470 @default.
• W2013981452 creator A5089813280 @default.
• W2013981452 date "2005-01-07" @default.
• W2013981452 modified "2023-09-22" @default.
• W2013981452 title "Synthesis and Structures of Cycloalkylidene-Bridged Cyclopentadienyl Metallocene Catalysts: Effects of the Bridges of Ansa-Metallocene Complexes on the Catalytic Activity for Ethylene Polymerization" @default.
• W2013981452 cites W1523647952 @default.
• W2013981452 cites W1963779283 @default.
• W2013981452 cites W1964749985 @default.
• W2013981452 cites W1964781706 @default.
• W2013981452 cites W1966497026 @default.
• W2013981452 cites W1968015622 @default.
• W2013981452 cites W1969292265 @default.
• W2013981452 cites W1969766958 @default.
• W2013981452 cites W1970040131 @default.
• W2013981452 cites W1974472539 @default.
• W2013981452 cites W1974481547 @default.
• W2013981452 cites W1989959989 @default.
• W2013981452 cites W1991436567 @default.
• W2013981452 cites W1996888732 @default.
• W2013981452 cites W2006323566 @default.
• W2013981452 cites W2010327351 @default.
• W2013981452 cites W2014405819 @default.
• W2013981452 cites W2014740207 @default.
• W2013981452 cites W2016009189 @default.
• W2013981452 cites W2017483409 @default.
• W2013981452 cites W2017794085 @default.
• W2013981452 cites W2018145329 @default.
• W2013981452 cites W2028058466 @default.
• W2013981452 cites W2034187729 @default.
• W2013981452 cites W2036389903 @default.
• W2013981452 cites W2045391820 @default.
• W2013981452 cites W2047411755 @default.
• W2013981452 cites W2049323420 @default.
• W2013981452 cites W2051594970 @default.
• W2013981452 cites W2063225345 @default.
• W2013981452 cites W2064325329 @default.
• W2013981452 cites W2067529786 @default.
• W2013981452 cites W2078224009 @default.
• W2013981452 cites W2078690090 @default.
• W2013981452 cites W2084587520 @default.
• W2013981452 cites W2087265941 @default.
• W2013981452 cites W2094019850 @default.
• W2013981452 cites W2094783956 @default.
• W2013981452 cites W2105749556 @default.
• W2013981452 cites W2115249485 @default.
• W2013981452 cites W2153900045 @default.
• W2013981452 cites W2162510578 @default.
• W2013981452 cites W2165325400 @default.
• W2013981452 cites W2172207262 @default.
• W2013981452 cites W2173801568 @default.
• W2013981452 cites W2320745181 @default.
• W2013981452 cites W2325217651 @default.
• W2013981452 cites W2328278157 @default.
• W2013981452 cites W2950138506 @default.
• W2013981452 cites W4236898704 @default.
• W2013981452 doi "https://doi.org/10.1002/chem.200400750" @default.
• W2013981452 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15578691" @default.
• W2013981452 hasPublicationYear "2005" @default.
• W2013981452 type Work @default.
• W2013981452 sameAs 2013981452 @default.
• W2013981452 citedByCount "21" @default.
• W2013981452 countsByYear W20139814522012 @default.
• W2013981452 countsByYear W20139814522014 @default.
• W2013981452 countsByYear W20139814522019 @default.
• W2013981452 countsByYear W20139814522020 @default.
• W2013981452 countsByYear W20139814522021 @default.
• W2013981452 countsByYear W20139814522022 @default.
• W2013981452 countsByYear W20139814522023 @default.
• W2013981452 crossrefType "journal-article" @default.
• W2013981452 hasAuthorship W2013981452A5003653567 @default.
• W2013981452 hasAuthorship W2013981452A5006871407 @default.
• W2013981452 hasAuthorship W2013981452A5011394437 @default.
• W2013981452 hasAuthorship W2013981452A5011843698 @default.
• W2013981452 hasAuthorship W2013981452A5017431309 @default.
• W2013981452 hasAuthorship W2013981452A5018984822 @default.
• W2013981452 hasAuthorship W2013981452A5027455656 @default.
• W2013981452 hasAuthorship W2013981452A5052569205 @default.
• W2013981452 hasAuthorship W2013981452A5068762123 @default.
• W2013981452 hasAuthorship W2013981452A5070692470 @default.
• W2013981452 hasAuthorship W2013981452A5089813280 @default.
• W2013981452 hasConcept C153953470 @default.
• W2013981452 hasConcept C161790260 @default.
• W2013981452 hasConcept C178790620 @default.
• W2013981452 hasConcept C181458950 @default.
• W2013981452 hasConcept C185592680 @default.
• W2013981452 hasConcept C188027245 @default.
• W2013981452 hasConcept C192562407 @default.

• next