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- W2013981862 abstract "Abstract From the analysis of the microwave spectra of ON 35 Cl and ON 81 Br in several vibrational excited states, vibro-rotational constants corresponding to the ν 2 and ν 3 vibrational modes have been determined for both molecules. In order to extract information on the anharmonic force field from these experimental data and anharmonicity x ij constants obtained by other authors, the semiempirical potential function suggested by Pliva has been used. A good agreement between experimental and calculated molecular constants for both nitrosyl halides was obtained by least squares calculations using a NX , b NX , c NX , b NO , c NO , b ϕ , c ϕ Pliva's parameters as variables for different values of a NO . Cubic and quartic force constants in internal displacement coordinates were derived. A comparison of the cubic constants with a constrained cubic GVFF was also carried out." @default.
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- W2013981862 date "1978-06-01" @default.
- W2013981862 modified "2023-09-24" @default.
- W2013981862 title "Anharmonic force field of ONCl and ONBr by combination of infrared and microwave data" @default.
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- W2013981862 doi "https://doi.org/10.1016/0022-2852(78)90092-9" @default.
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