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- W2013983678 abstract "Abstract 5- and 6-nitrobenzoxazoles 3 and 4 react with nucleophiles exclusively at C-2, giving ring opening products. If position 2- is blocked with phenyl substituent the reaction takes place in the carbocyclic ring affording the VNS products. 2-Methylthio-5-nitrobenzoxazole 7 and its 6-nitro isomer 8 give products which result from addition of a nucleophile to the carbocyclic ring (VNS) as well as to the heterocyclic ring (SNAr and ring cleavage). 2-Methylthiobenzoxazoles can be readily converted to the corresponding benzoxazolones via oxidative hydrolysis." @default.
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- W2013983678 date "1995-06-01" @default.
- W2013983678 modified "2023-10-18" @default.
- W2013983678 title "The vicarious nucleophilic substitution of hydrogen and related reactions in nitrobenzoxazoles" @default.
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- W2013983678 doi "https://doi.org/10.1016/0040-4020(95)00351-8" @default.
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