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- W2013990890 abstract "The complex Rh (OH) (CO) (PPh3)in homogeneous as well as in γ-Al2O3 supported system was used as catalyst precursor for hex-1-ene and benzene hydrogenation at 80°C and 6.5 atm of H2. The hydride complexes, HRh (CO) (PPh3)3 and HRh (CO) (PPh3), identified by 1H and 31p NMR studies, were found to be the active forms in the homogeneous system. γ-Al2O3 supported Rh (OH) (CO) (PPh3)2 complex, activated for 2 h in hydrogen atmosphere does not change its catalytic activity for four weeks. X-ray diffraction spectra show that hydrogenation proceeds with participation of rhodium complexes rather than rhodium metal catalytic centers." @default.
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- W2013990890 date "1994-02-01" @default.
- W2013990890 modified "2023-10-17" @default.
- W2013990890 title "Homogeneous and alumina supported rhodium complex catalysed hydrogenation" @default.
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- W2013990890 doi "https://doi.org/10.1016/0304-5102(93)e0249-g" @default.
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