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• W2013991574 abstract "During the last decade the synthesis and heparin-like properties of Carboxymethyl Dextran Benzylamide Sulfonate (CMDBS) have been investigated extensively. The carboxymethylation of the sugar hydroxyl groups of dextrans is the first and determining step during the CMDBS synthesis. The kinetics of this reaction as well as the structure of the resulting carboxymethylated compounds (CMD) have been investigated by joint 1D and 2D 1H13C NMR spectroscopies. Using the corresponding data within kinetic equations provided 9 rate coefficients of carboxymethylation. At the same time Monte Carlo simulations of the CMDBS structures taking the NMR data and making some simplified assumptions allowed the analysis of the subsequent benzylamidification and sulfonation steps. Structure-function relationships, based on the preliminarly Monte Carlo results and anticoagulant properties of CMDBS, indicated that the anticoagulant activity of these compounds can be explained in terms of units distribution along the polymer chain." @default.
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• W2013991574 date "1997-05-01" @default.
• W2013991574 modified "2023-10-17" @default.
• W2013991574 title "Anticoagulant activity of functionalized dextrans. Structure analyses of carboxymethylated dextran and first Monte Carlo simulations" @default.
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• W2013991574 doi "https://doi.org/10.1016/s0144-8617(96)00173-7" @default.
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