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- W2013996864 abstract "The principal crystalline and molecular susceptibilities, and their orientations, of cobalt(II) phthalocyanine, [Co(pc)], bis(pentane-2,4-dithionato)cobalt(II). [Co(pdt)2]. copper(II) phthalocyanine, [Cu(pc)], and bis-(pentane-2,4-dionato)copper(II), [Cu(pd)2], are reported. The diamagnetic anisotropy of the two pc derivatives makes a significant contribution to the observed anisotropy, especially in the cooper compound. The resulting paramagnetic anisotropy {and e.s.r. data in the case of [Co(pdt)2]} is then used to confirm the S=½ ground state of each compound [⋯ dz21 in both the cobalt(II) derivatives and dxy1 in both the copper(II) derivatives]. The marked in-plane anisotropy in [Co(pdt)2], compared with the in-plane isotropy of [Co(pc)], is shown to arise from both the abnormally large splitting of the dxz, dyz pair of orbitals and the mixing of the dxy and dz2 orbitals in low symmetry. An unambiguous assignment of two of the excited states in [Cu(pc)] can be made but ambiguities remain in [Cu(pd)2]." @default.
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- W2013996864 date "1976-01-01" @default.
- W2013996864 modified "2023-10-06" @default.
- W2013996864 title "Paramagnetic anisotropy of planar cobalt(II) and copper(II) phthalocyanine, bis(pentane-2,4-dionato)copper(II), and bis(pentane-2,4-dithionato)cobalt(II)" @default.
- W2013996864 doi "https://doi.org/10.1039/dt9760001458" @default.
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