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- W2013998077 abstract "The total synthesis of (−)-denticulatin B (2) was achieved in 9 steps (20% yield), with 70% overall diastereoselectivity, starting from the ethyl ketone (R)-9. Most of the stereochemistry was introduced by substratebased control. Key steps include the boron-mediated aldol/reduction, 9 → 22, the titanium-mediated aldol coupling, 26 + 8 → 38, and the directed cyclisation, 35 → 2. Epimerisation at C10 in 35 led to (−)-denticulatin A (1)." @default.
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- W2013998077 date "1996-01-01" @default.
- W2013998077 modified "2023-10-07" @default.
- W2013998077 title "Total Synthesis of (−)-Denticulatins A and B Using Efficient Methods of Acyclic Stereocontrol." @default.
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- W2013998077 doi "https://doi.org/10.1016/0040-4020(95)01015-7" @default.
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