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- W2014001479 abstract "Peroxopolyoxotungsten-based hybrid catalysts modified by dicationic long-chain alkyl imidazolium cations have been synthesized and characterized. The catalytic activity of the catalysts was measured for the epoxidation of olefins with H 2 O 2 . These catalysts proved to be high catalytic activity phase transfer catalysts. In particular, for the catalyst [D 12 min] 1.5 PW 4 O 24 modified by the dodecyl dicationic imidazolium cation, the conversion of cyclohexene and selectivity for epoxycyclohexane were 97.7% and 96.3%, respectively. After the reaction, the catalyst could be recovered simply by filtration and reused four times. The conversion of cyclohexene and selectivity for epoxycyclohexane were still 72.4% and 97.2%, respectively, after recycling the catalyst four times. In addition, this phase transfer catalyst can be applied to the epoxidation of a wide range of olefins. Peroxopolyoxotungsten-based hybrid catalysts modified by the dicationic long-chain alkyl imidazolium cation were synthesized and used as the phase transfer catalyst for cyclohexene epoxidation reactions." @default.
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- W2014001479 date "2013-12-01" @default.
- W2014001479 modified "2023-09-30" @default.
- W2014001479 title "Synthesis of dicationic alkyl imidazolium peroxopolyoxotungsten-based phase transfer catalyst and its catalytic activity for olefin epoxidation" @default.
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- W2014001479 doi "https://doi.org/10.1016/s1872-2067(12)60697-4" @default.
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