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- W2014004087 abstract "Abstract For some polystyrene–poly(methyl methacrylate) block copolymers whose second blocks are prepared in a free‐radical reaction, a decrease in intrinsic viscosity appears by simple heating in a solvent. Contrary to our previous explanation, this decrease is now explained as related, not to a cleavage of a covalent bond, but to an intramolecular rearrangement of the structure. This was shown by viscosity light‐scattering and gel chromatography measurements. It seems that the free‐radical polymerization leads to an unstable structure, which is transformed into a more stable one during the heating. It is possible that in the first form the different blocks are intermingled and that they become segregated in the stable form. Under the same conditions no variation appears when the block copolymers are entirely formed by an ionic mechanism. In this case we may believe that they are already formed in the stable structure." @default.
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- W2014004087 date "1968-01-01" @default.
- W2014004087 modified "2023-09-26" @default.
- W2014004087 title "Sur un Cas Particulier de Réarrangement Intramoléculaire des Copolymères Séquencés en Solution" @default.
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- W2014004087 doi "https://doi.org/10.1002/polc.5070220129" @default.
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