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- W2014018366 abstract "Treatment of NaO 2 CCH C(Me)Fc with cadmium acetate and iron(II) sulfate in the presence of 2,2′-bipy yielded [Cd 2 Fe(μ-O 2 CCH C(Me)Fc) 2 (μ 2 -O 2 CCH C(Me)Fc) 2 (μ 2 -η 2 -O 2 CCH C(Me)Fc) 2 (2,2′-bipy) 2 ] · 2H 2 O ( 1 ); while from NaO 2 CC 6 H 4 {C(O)Fc- o }, cadmium acetate, and pbbm the product was {[Cd(η 2 -O 2 CC 6 H 4 {C(O)Fc- o }) 2 (pbbm)] · 0.5H 2 O} n ( 2 ) [Fc = (η 5 -C 5 H 5 )Fe(C 5 H 4 -η 5 ); 2,2′-bipy = 2,2′-bipyridyl; pbbm = 1,1′-(1,5-pentamethylene)bis-1 H -benzimidazole]. Compounds 1 and 2 have been characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. In centro-symmetric crystalline 1 , the Fe and the two flanking atoms are six-coordinate; the three carboxylato ligands between the Fe and a Cd atom have different coordination modes. Crystalline 2 consists of an infinite polymeric chain, in which adjacent [Cd(η 2 -O 2 CC 6 H 4 {C(O)Fc- o }) 2 ] units are linked by pbbm ligands; thus each Cd atom is six-coordinate. Some electrochemical properties of the two complexes are reported." @default.
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- W2014018366 date "2009-07-01" @default.
- W2014018366 modified "2023-09-26" @default.
- W2014018366 title "A heterotrinuclear and a polynuclear complex constructed from a ferrocenyl carboxylate and an N-containing ligand: Synthesis, crystal structures and electrochemical properties" @default.
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- W2014018366 doi "https://doi.org/10.1016/j.ica.2009.02.008" @default.
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