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- W2014030038 abstract "The solid-melt equilibria curve between Na β″-Al2O3 powder and Na-K chloride melts at 810°C has been obtained together with an accurate determination of the β″-Al2O3 cell parameters for the entire Na-K composition range. The activities and their coefficients, chemical potentials and free energies for the different Na-K compositions have been calculated. Analysis of these thermodynamic properties indicates that K+ strongly prefers the β″-Al2O3 phase and K β- and β″-Al2O3 are thermodynamically more stable than the Na analogs. The Na+ and K+ ions repulsively interact for 0<[K+]<0.93 and attract for [K+]>0.93. These interactions are reflected by increases and decreases of the a0 lattice parameter." @default.
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- W2014030038 date "1986-08-01" @default.
- W2014030038 modified "2023-09-26" @default.
- W2014030038 title "Ion exchange and thermodynamic studies on (Na-K) β″-alumina" @default.
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- W2014030038 doi "https://doi.org/10.1016/0167-2738(86)90010-x" @default.
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