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- W2014036637 abstract "The photomagnetic effect of the mixed-valence compound Cu2II[MoIV(CN)8]·7.6H2O (CuII; 3d9, S=1/2, MoIV; 4d2, S=0) (1) was investigated. The UV–VIS spectra showed the intervalence transfer (IT) band between MoIV–CN–CuII and MoV–CN–CuI around 500 nm. When the paramagnetic compound 1 was irradiated by a filtered blue light (400–430 nm, 3 mW/cm2) of a Xe lamp at 5 K, the irradiated sample exhibited a spontaneous magnetization with a Curie temperature of 17 K. By annealing the irradiated sample above 200 K, the magnetic property of this sample returned to the initial state. This photo-induced magnetization is explained by the following mechanism. The excitation of the IT band causes the electron transfer from MoIV (S=0) to CuII (S=1/2), producing a mixed-valence isomer of MoV (S=1/2)–CN–CuI (S=0). However, half of the copper ions remain as CuII ions due to the stoichiometric limitation and hence the irradiated 1 is expressed as CuICuII[MoV(CN)8]·7.6H2O. The unpaired electrons on MoV (S=1/2) ions and those on CuII (S=1/2) ions in the irradiated compound interact ferromagnetically, giving rise to the spontaneous magnetization." @default.
- W2014036637 created "2016-06-24" @default.
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- W2014036637 date "2001-08-01" @default.
- W2014036637 modified "2023-10-18" @default.
- W2014036637 title "Photo-induced magnetization in copper(II) octacyanomolybdate(IV)" @default.
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- W2014036637 doi "https://doi.org/10.1016/s0379-6779(01)00327-7" @default.
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