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- W2014080497 abstract "Chiral hybrid organic–inorganic materials were prepared by anchoring optically active β-aminoalcohols such as (−)-ephedrine on MCM-41 type silica as a member of micelle-templated silicas (MTS). Silylation of the surface was performed with halogenopropyltrimethoxysilane. Then, (−)-ephedrine was anchored through halogen substitution. These materials were used as chiral auxiliaries in the heterogeneous enantioselective catalysis of the alkylation of benzaldehyde by diethylzinc. This work deals with the study of the various factors such as accessibility to the catalytic sites and coverage of the inorganic surface, which affect their efficiency (activity, selectivity and enantioselectivity)." @default.
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- W2014080497 title "Factors affecting the efficiency of hybrid chiral mesoporous silicas used as heterogeneous inorganic–organic catalysts in the enantioselective alkylation of benzaldehyde" @default.
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- W2014080497 doi "https://doi.org/10.1016/s0957-4166(99)00310-9" @default.
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