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- W2014090368 abstract "Nos études sur les composés oxygènés du thallium I nous ont conduit à proposer un modèle permettant le calcul, sur une base électrostatique, de la position du doublet solitaire (appelé paire non liée par divers auteurs). Le principe de ce calcul consiste à évaluer le champ au niveau du thallium I et, connaissant sa polarisabilité, à déterminer la position du doublet solitaire dont le déplacement traduit la polarisation du thallium I. La méthode exposée est applicable à tout ion comportant un doublet solitaire et dont la polarisabilité est connue (ex. PbII). Les approximations liées à la nature du modèle proposé et les limites de validité sont discutées. Our general studies on various solid compounds in the Tl(I)OM systems (M = B, Tl, C, Si, Ti, Sn, P, Sb) lead us to propose an electrostatic model from which the lone pair positions are determined by calculation. The principle of calculation consists of evaluating the electric field at the Tl(I) nucleus. Knowing the polarizability of Tl(I) the lone pair position may be determined. The above method is applicable for any ion having a lone pair and for which the polarizability is known. Approximations related to the nature of the proposed model along with limits of application are discussed." @default.
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- W2014090368 date "1978-01-01" @default.
- W2014090368 modified "2023-10-18" @default.
- W2014090368 title "Localisation du doublet solitaire dans les composés oxygènés cristallisés du thallium I" @default.
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- W2014090368 doi "https://doi.org/10.1016/0022-4596(78)90088-9" @default.
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