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- W2014093043 abstract "Oxidation of prochiral and racemic cyclobutanones with t-BuOOH and Ti–TADDOL-based complexes afforded lactones in up to 44% ee. The enantioselectivity of the reaction clearly depends on the amount of the reagent and the highest enantioselectivities were obtained with stoichiometric amounts of the complex. Modification of the TADDOL structure and use of the mixed complex derived from TADDOL and a tartaric ester led to more reactive but less selective oxidation systems." @default.
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- W2014093043 date "1998-12-01" @default.
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- W2014093043 title "Asymmetric oxidation of cyclobutanones: modification of the Sharpless catalyst" @default.
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