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- W2014093370 abstract "Reduced-sugar based gemini surfactants with an α,ω-diamino-(oxa)alkyl spacer exhibit a rich pH-dependent aggregation behavior and are efficient DNA carriers in gene transfection. Herein, we describe an improved synthetic procedure for these amphiphiles. First, a series of novel nonionic bolaform amphiphiles with identical headgroups and α,ω-diamino-(oxa)alkyl spacers were synthesized by reductive aminations involving α,ω-diaminoalkanes and the appropriate sugars or aldehydes. The bolaform compounds were used as starting materials for the synthesis of the corresponding reduced-sugar based gemini surfactants in a reductive alkylation reaction employing a polymer-bound cyanoborohydride. A series of new gemini surfactants have been synthesized and characterized." @default.
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- W2014093370 date "2007-10-01" @default.
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- W2014093370 title "Synthesis of nonionic reduced-sugar based bola amphiphiles and gemini surfactants with an α,ω-diamino-(oxa)alkyl spacer" @default.
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- W2014093370 doi "https://doi.org/10.1016/j.tet.2007.08.023" @default.
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