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- W2014096987 abstract "The cyclotetrasilane [(i-Pr)2Si]4 reacts with K in benzene in the presence of 18-crown-6 to give the 1,4-dipotassio compound K[(i-Pr)2Si]4 K (1). The reaction of 1 with (i-Pr)2SiCl2 and Me3SiCl leads to the formation of the sterically crowded oligosilanes, [(i-Pr)2Si]5 (2) and Me3Si[(i-Pr)2Si]4SiMe3 (3), respectively. The molecular structures of the resulting oligosilanes, 2 and 3, display some unusual features." @default.
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- W2014096987 date "1999-07-01" @default.
- W2014096987 modified "2023-09-24" @default.
- W2014096987 title "Synthesis and Molecular Structures of Novel Isopropyl-substituted Oligosilanes" @default.
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- W2014096987 doi "https://doi.org/10.1246/cl.1999.595" @default.
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