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- W2014118568 abstract "Activation parameters for solvent exchange of the title complex in N,N-dimethylformamide (DMF) have been determined as follows: k(25°C)=(3.4±0.2)×107 s−1, ΔHeweq=18±3 kJ−1 mol−1, ΔSeweq=−40±10 J K−1 mol−1, and ΔVeweq=10±2 cm3 mol−1. The positive value of ΔVeweq indicates that the DMF exchange proceeds via a dissociative interchange mechanism." @default.
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- W2014118568 date "1991-06-01" @default.
- W2014118568 modified "2023-09-27" @default.
- W2014118568 title "Solvent Bulkiness Effect on<i>N</i>,<i>N</i>-Dimethylformamide Exchange of the<i>o</i>-Phenylenediamine-<i>N</i>,<i>N</i>,<i>N</i>′,<i>N</i>′-tetraacetatoferrate(III) Complex as Studied by a High-Pressure NMR Method" @default.
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- W2014118568 doi "https://doi.org/10.1246/bcsj.64.1988" @default.
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