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- W2014123560 abstract "We present specific heat experiments on ${mathrm{CF}}_{2}{mathrm{Cl}}_{2}$ monolayers physisorbed on graphite and determine the entropy changes at the structural and melting phase transitions. The results confirm previously reported x-ray studies where a phase sequence from a low-temperature commensurate hexagonal phase to an incommensurate triangular mesophase and finally the liquid phase was observed. The temperature dependence of the excess entropy reveals that the low temperature phase is orientationally ordered. Angular disorder with respect to reorientation around the surface normal evolves in the mesophase, and is fully developed just below the melting transition where the molecule starts to rotate around an axis parallel to the surface. We observe strong evidence for two-dimensional random exchange or random field behavior at the melting transition of the mesophase due to the bond disorder produced by the rotation about an axis parallel to the surface." @default.
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- W2014123560 date "2000-01-15" @default.
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- W2014123560 title "Orientational disorder and melting of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>CF</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Cl</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>monolayers physisorbed on graphite" @default.
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- W2014123560 doi "https://doi.org/10.1103/physrevb.61.3028" @default.
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