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- W2014124780 abstract "The title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(η3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4′-di-tert-butyl-2,2′-bipyridine). A μ-oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually cis, and the chloride and μ-oxide trans to each other. In the binuclear complex, the coordination geometries of the metal atoms can be described as highly distorted octahedra. Individual complexes co-crystallize with a partially occupied water molecule of crystallization (occupancy factor = 0.20; H atoms not located), with the crystal packing being mediated by the need to effectively fill the available space. A number of weak C—H⋯O and C—H⋯Cl interactions are present." @default.
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- W2014124780 date "2011-11-12" @default.
- W2014124780 modified "2023-09-27" @default.
- W2014124780 title "μ-Oxido-bis[chlorido(4,4′-di-<i>tert</i>-butyl-2,2′-bipyridine-κ<sup>2</sup><i>N</i>,<i>N</i>′)dioxidomolybdenum(VI)] 0.2-hydrate" @default.
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- W2014124780 doi "https://doi.org/10.1107/s1600536811046952" @default.
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