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- W2014128761 abstract "The in-situ composites of polyamide 6 (PA 6)/liquid crystalline polymer (LCP) were investigated from the standpoint of fibrillation of LCP to develop a new high performance gear material for heavy load use that is superior to conventional plastic gears made of polyacetal (POM). LCP used was a wholly aromatic copolyester. PA 6 was chosen as the matrix polymer because of its excellent fatigue resistance. Extrusion of PA 6 added with LCP from 10 to 30 vol% was carried out at a temperature between 260 and 290°C by a twin screw extruder and take-up equipment. Insitu fibrillation of LCP droplets, which were dispersed in PA 6 matrix, took place during the process. Injection molding of the composites was followed at a temperature below the softening point of LCP fibrils so as to keep the fibrils as extruded. Key factors for fibrillation of LCP were found as follows: (1) control of stress relaxation of LCP when the melt passes through the die-head, (2) the optimum temperature of nent, (3) the optimum LCP content, and (4) addition of a small amount of 3rd component. A gear made of in-situ composite of PA 6/LCP (30 vol%) added with 2-functional epoxy resin (2.5 phr) was found to bear a load about 1.2 times heavier than a POM gear." @default.
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- W2014128761 date "1999-05-01" @default.
- W2014128761 modified "2023-09-25" @default.
- W2014128761 title "Reinforcement of polyamide 6 with thermotropic liquid crystalline polymer" @default.
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- W2014128761 doi "https://doi.org/10.1002/pen.11476" @default.
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