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- W2014131025 abstract "Abstract In dichloromethane, the hydroxo-complexes [NBu4]2[{M(C6X5)2(μ-OH)}2] [M = Pd (X = F or Cl) or Pt (X = F)] and [{Pd(C5X5)(PPh3)(μ-OH)}2] (X = F or Cl) react with amines in the presence of carbon disulfide to give the corresponding dithiocarbamate complexes [NBu4][M(C6X5)2(S2CNR2)] [M = Pd, X = F and R Me (I), Et (II), or C4H8 (III); M = Pd, X = Cl and R = Me (IV) or Et (V); M = Pt, X = F and R = Me (VI) or Et (VII)] and [Pd(C6X5)(PPh3)(S2CNR2)] [X = F and R = Me (VIII) or Et (IX); X = Cl and R = Me (X) or Et (XI)]. Conductance measurements and spectroscopic (IR, 1H and 19F NMR) methods have been used for structural assignments." @default.
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- W2014131025 date "1992-09-01" @default.
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- W2014131025 title "Synthesis of palladium(II) and platinum(II) N,N-dialkyldithiocarbamates starting from hydroxo-halophenyl complexes" @default.
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- W2014131025 doi "https://doi.org/10.1016/0022-328x(92)85033-s" @default.
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