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- W2014132860 abstract "Low-temperature plasma polymerization is a promising pretreatment technique to create environmentally friendly coating systems for corrosion protection of aluminum alloys. In this study, the pretreatment effects of plasma treatment and plasma polymerization on corrosion properties of alclad aluminum alloy 2024-T3 ([2A]) were investigated using electrochemical characterization techniques, including cyclic polarization (CP) and electrochemical impedance spectroscopy (EIS). The [2A] panels were coated with an ultrathin layer (∼50nm) of plasma polymers in a direct current (dc) glow discharge of trimethylsilane or its mixtures with one of two diatomic gases (O2 and N2). The CP measurement results showed that the plasma polymer coated [2A] panels exhibited more negative corrosion potentials (Ecorr), smaller corrosion currents (Icorr), and no surface passivation when compared with uncoated [2A] control panels. The lower values of Icorr imply a higher corrosion resistance on the plasma polymer coated [2A]. When investigated using EIS, these plasma polymer coated [2A] panels exhibited higher impedance (∣Z∣) at lower frequency when first immersed in electrolyte solution, yet degraded quickly to a similar level as uncoated controls within 1day of immersion. These results illustrated that thin plasma polymer films provided a certain but very limited corrosion resistance to [2A] substrate; their dominant role in plasma interface engineered coating systems still relied mostly on their adhesion enhancement at metal∕paint interface as observed in our previous studies." @default.
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- W2014132860 date "2005-06-27" @default.
- W2014132860 modified "2023-09-26" @default.
- W2014132860 title "Electrochemical characterization of plasma polymer coatings in corrosion protection of aluminum alloys" @default.
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- W2014132860 doi "https://doi.org/10.1116/1.1924716" @default.
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