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- W2014144438 abstract "X-ray diffraction patterns of NaAlH4 doped with up to 10 mol.% of either titanium or zirconium do not contain Bragg peaks for the bulk metals or their aluminum alloys. Instead the hydride lattice parameters a and c undergo significant contraction upon 2 mol.% doping and then expand as the doping level increases from 2 to 5 mol.%. These results are explained by a model that entails substitution of sodium cations by variable valence transition metal cations and the creation of Na+ vacancies in the bulk hydride lattice." @default.
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- W2014144438 date "2002-05-01" @default.
- W2014144438 modified "2023-10-09" @default.
- W2014144438 title "X-ray diffraction studies of titanium and zirconium doped NaAlH4: elucidation of doping induced structural changes and their relationship to enhanced hydrogen storage properties" @default.
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- W2014144438 doi "https://doi.org/10.1016/s0925-8388(01)01955-7" @default.
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