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• W2014157033 abstract "The vacuum-ultraviolet photolysis of methane in an argon or a nitrogen matrix at 14°K leads to the formation of a sufficient concentration of the methyl radical for observation both of its 1500-Å electronic transitions and of its out-of-plane deformation fundamental, which appears at 611 cm−1 for CH3 trapped in a nitrogen matrix. The value observed for this fundamental of CD3 is in reasonable agreement with the value previously derived from analysis of the 2160-Å band system. Isotopic substitution studies support the assignment of the 611-cm−1 feature to ν2 of CH3. Data are consistent with the previous report of a planar structure. Evidence is presented suggesting that CH3 may rotate in an argon matrix. Although CH2 has not been directly observed, an appreciable concentration of CH2N2 appears in the N2 matrix experiments. Three electronic transitions of CH are observed in the argon matrix experiments, and there is evidence for the production of a small concentration of C atoms." @default.
• W2014157033 created "2016-06-24" @default.
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• W2014157033 date "1967-12-15" @default.
• W2014157033 modified "2023-10-05" @default.
• W2014157033 title "Infrared and Ultraviolet Spectroscopic Study of the Products of the Vacuum-Ultraviolet Photolysis of Methane in Ar and N2 Matrices. The Infrared Spectrum of the Free Radical CH3" @default.
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• W2014157033 doi "https://doi.org/10.1063/1.1701772" @default.
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