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- W2014164001 abstract "The reaction of SO2 with Ir4(CO)11(norborn-2-ene) yields Ir4(CO)9(μ2-CO)2(μ2-SO2) (i). X-ray diffraction shows that I contains a sulphur dioxide ligand and two CO groups, all three bridging between two basal metal atoms. The lowest-energy CO scrambling process for I has been determined by 13C NMR studies. The thermal stability and high solubility of I (compared to Ir4(CO)12) make it a good starting material for the synthesis of other tetrairidium clusters." @default.
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- W2014164001 date "1985-04-01" @default.
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- W2014164001 title "A tetrairidium cluster with a bridging SO2: The synthesis, fluxional behaviour, and crystal structure of Ir4(CO)9(μ2-CO)2(μ2-SO2)" @default.
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- W2014164001 doi "https://doi.org/10.1016/0022-328x(85)87246-6" @default.
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