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- W2014166747 abstract "From observable ion studies on a series of polymethyl tertiary 2-norbornyl cations, a huge difference in the migratory aptitudes (stereospecificity) of 3-exo and 3-endo methyl groups was observed. The same trend was observed under typical acid catalysis conditions where the same rearrangements are involved but where the cation is in this case a fleeting intermediate. In related work, a comparison was made of the absolute rate of an exo-3,2-hydride and an exo-3,2-methyl shift and a direct measurement of the H–D isotope effect in a 3,2-hydride shift was made." @default.
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- W2014166747 date "1975-04-01" @default.
- W2014166747 modified "2023-10-12" @default.
- W2014166747 title "A Comparison of the Stereospecificity of Carbocation to Rearranged Carbocation Reactions under Observable Ion and Steady-state Intermediate Conditions" @default.
- W2014166747 doi "https://doi.org/10.1139/v75-150" @default.
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