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- W2014171094 abstract "Stereochemistry crossover from retention to inversion of configuration at about −20 °C was observed in the nucleophilic substitution of optically active (R)-fluoromethyl(1-naphthyl)phenylsilane ((R)-2F; >99% ee) with the achiral silyllithium species (dimethyl(4-methoxynaphth-1-yl)silyl)lithium (1) to give optically active 1,1,2-trimethyl-2-(4-methoxy-1-naphthyl)-1-(1-naphthyl)disilane (3). It became possible to synthesize both enantiomerically pure stereoisomers of disilane with one chiral center from a single antipode of the fluorosilane enantiomer by using HMPA, LiClO4, LiBr as additives, or by changing the temperature." @default.
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- W2014171094 date "2003-05-13" @default.
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- W2014171094 title "Selective Formation of Both Enantiomerically Pure Disilanes from One Fluorosilane Antipode with Silyllithium" @default.
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- W2014171094 doi "https://doi.org/10.1021/om030139t" @default.
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