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- W2014174943 abstract "In order to design artificial chemical systems that are capable of achieving complex functions, it is useful to design synthetic receptors that mimic their biological counterparts. Biological functions are underpinned by properties that include specific binding with high affinity and selectivity, cooperativity, and release triggered by external stimuli. Here we show that a metal–organic receptor constructed through subcomponent self-assembly can selectively and cooperatively load and release oxocarbon anions. The flexible coordination spheres of its cadmium(II) centers allow the receptor to dynamically adjust its structure upon exchanging four triflate or triflimide counterions for two oxocarbon anions, resulting in strong cooperativity and very tight binding, with an apparent association constant for C5O52– of 5 × 1010 M–1. Substituting the cadmium(II) ions for copper(I) by switching solvent prompted a structural reorganization and release of the oxocarbon anions. Its cooperative behavior allows the receptor to carry a greater payload than would be possible in a noncooperative analogue." @default.
- W2014174943 created "2016-06-24" @default.
- W2014174943 creator A5008423869 @default.
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- W2014174943 creator A5034004588 @default.
- W2014174943 creator A5056984509 @default.
- W2014174943 creator A5067799157 @default.
- W2014174943 date "2015-02-02" @default.
- W2014174943 modified "2023-09-25" @default.
- W2014174943 title "Cooperative Loading and Release Behavior of a Metal–Organic Receptor" @default.
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- W2014174943 doi "https://doi.org/10.1021/ja5120437" @default.
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