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• W2014186255 abstract "The chemical reactivity of benzene cations in medium-sized (n ∼ 25) (H2O)n water clusters has been investigated. After formation in a supersonic jet, the neutral Bz-(H2O)n species are ionized by resonance-enhanced two-photon ionization. The existence of magic numbers in the mass spectra of these cluster ions has been revealed by reflectron time-of-flight mass spectrometry. These magic numbers are assigned to size-dependent evaporation processes following the ionization. The similarities observed for the present magic numbers compared to those of protonated water clusters allow us to assign them to the formation of a protonated water cluster without ejection of the benzenoid product from the cluster ion. With this diagnosis, we present evidence for the existence of a size-dependent chemical reactivity of benzene cations: a reaction is observed in the medium size range (n ∼ 20−30), whereas small clusters are known not to react. This result is compared to the chemical reactivity of toluene+ in water clusters as well as to experimental data concerning liquid phase reactions." @default.
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• W2014186255 date "1997-02-01" @default.
• W2014186255 modified "2023-09-27" @default.
• W2014186255 title "Chemistry of Aromatic Cations on Water Clusters: Magic Numbers as a Mass Spectroscopic Diagnosis of Reactivity" @default.
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• W2014186255 doi "https://doi.org/10.1021/jp962389b" @default.
• W2014186255 hasPublicationYear "1997" @default.
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