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• W2014191505 startingPage "5070" @default.
• W2014191505 abstract "Silver(I) complexes of [9]aneS3, [15]aneS5, and [18]aneS6 have been used as templates for the self-assembly of polyiodide ions. The complexes [Ag2([15]aneS5)2]I12, [Ag([18]aneS6)]I7, [Ag([18]aneS6)]I3, and [Ag([9]aneS3)2]I5 have been synthesized and structurally characterized. In [Ag2([15]aneS5)2]I12 [C10H20AgI6S5, orthorhombic, space group Pna21 with a = 21.688(4) Å, b = 27.748(4) Å, c = 8.623(2) Å, Z = 8], a discrete I122- polyiodide anion describable as a [2I-·5I2] charge-transfer adduct is bound to two [Ag([15]aneS5)]+ cations by Ag−I bonds. I···S interactions contribute to build up an extended three-dimensional superstructure featuring spirals of I122- and [Ag([15]aneS5)]+ ions alternating along the c axis. In [Ag([18]aneS6)]I7 [C12H24AgI7S6, trigonal, space group R3̄m with a = b = c = 9.458(4) Å, α = β = γ = 103.79(3)°, Z = 1], the Ag(I) complex cation is embedded in a unique three-dimensional polyiodide matrix in which I- ions occupy the lattice points of a primitive rhombohedral lattice with one I2 molecule bridging two I- ions along each cell edge to give a pseudo-perovskite structure. [Ag([18]aneS6)]I3 [C12H24AgI3S6, monoclinic, space group C2/m with a = 18.5767(11) Å, b = 11.9188(7) Å, c = 5.2714(5) Å, β = 95.634(9)°, Z = 2] features discrete [Ag([18]aneS6)]+ cations and I3- in a columnar stacking arrangement. Using the [Ag([9]aneS3)2]+ cation as template, an I5- salt has been obtained; this contrasts with the cubelike [I7-]∞ polyiodide array and I3- salt isolated with the [Ag([18]aneS6)]+ cation. In [Ag([9]aneS3)2]I5 [C12H24AgI5S6, monoclinic, space group C2/c with a = 17.1117(12) Å, b = 12.612(2) Å, c = 14.016(2) Å, β = 118.65(4)°, Z = 4], I···S interactions contribute to an extended structure featuring polymeric successions of cations and I5- ions. The solid-state FT-Raman spectra of these polyiodides are discussed on the basis of their crystal structures." @default.
• W2014191505 created "2016-06-24" @default.
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• W2014191505 date "1998-09-16" @default.
• W2014191505 modified "2023-09-25" @default.
• W2014191505 title "Silver−Thioether Crown Complexes as Templates for the Synthesis of Extended Polyiodide Networks: Synthesis and X-ray Crystal Structures of [Ag₂([15]aneS₅)₂]I₁₂, [Ag([18]aneS₆)]I₇, [Ag([18]aneS₆)]I₃, and [Ag([9]aneS₃)₂]I₅" @default.
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• W2014191505 doi "https://doi.org/10.1021/ic980413p" @default.
• W2014191505 hasPublicationYear "1998" @default.
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