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- W2014200122 abstract "Interest in fluorine-containing compounds has considerably grown in the last decade, due to their interesting properties. Mass spectrometry has proved to be a valid method for both the structural characterization and for the description of the intimate decomposition mechanism and of the possible structural features of this class of compounds. We report here a mass spectrometric study on some C6F13-containing compounds (esters and related acid, aldehyde, alcohol, phenylhydrazone), as obtained by using different ionization techniques, e.g. Fast Atom Bombardment (FAB) and Electron Impact (EI). As expected, under FAB conditions the fragmentation is quite poor and protonated molecular ions are easily detectable. Under EI conditions the induced decomposition patterns, as obtained by metastable ion studies, are strongly influenced by the presence of the C6F13-moiety. Decomposition routes different from those observed for the C6H13-analogues are activated and rationalized in terms of the stability of the product ions." @default.
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- W2014200122 date "1992-08-01" @default.
- W2014200122 modified "2023-09-26" @default.
- W2014200122 title "Fluorine influence in the mass spectrometric behaviour of some C6F13-containing compounds" @default.
- W2014200122 doi "https://doi.org/10.1016/s0022-1139(00)80755-1" @default.
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