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• W2014200220 abstract "Magnetic properties and crystal structures of pyridyl and pyridinium α-nitronyl nitroxides have been studied. The intermolecular magnetic coupling is ferromagnetic in the crystal of p-pyridyl α-nitronyl nitroxide (PYNN), while it is antiferromagnetic in m- or o-PYNN. The ferromagnetic properties of p-PYNN can be understood in terms of an one-dimensional (1D) ferromagnetic chain which is consistent with the molecular arrangement in the crystal. The temperature dependence of the magnetic susceptibilities of the m- and p-N-methylpyridinium α-nitronyl nitroxide (MPYNN) iodide salts are well fitted by the singlet-triplet model, although their intradimer magnetic couplings are opposites: it is ferromagnetic in m-MPYNN and it is antiferromagnetic in p-MPYNN. X-ray crystal analysis has been carried out using a stable crystal, m-MPYNN•(BF4)x•I1−x(x=0.72), showing that the molecules exist as a dimer, and the dimer units form a 2D triangular lattice." @default.
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• W2014200220 date "1993-04-01" @default.
• W2014200220 modified "2023-09-23" @default.
• W2014200220 title "Ferromagnetic properties and crystal structures of pyridyl and pyridinium α-nitronyl nitroxides" @default.
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• W2014200220 doi "https://doi.org/10.1016/0379-6779(93)90120-l" @default.
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